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Abstract Focused ultrasound (FUS) presents unique advantages for noninvasive localized heating, crucial for controlled shape recovery in shape memory polymers (SMPs), especially in biomedical applications. To enhance FUS-driven actuation efficiency, we propose boron nitride (BN)-infused SMP composites (SMPCs) tailored for targeted biomedical interventions. Using tert-butyl acrylate (tBA) and di(ethylene glycol) dimethacrylate as base materials, we integrated BN fillers at varying concentrations (1, 5, and 10 wt.%). A thorough characterization was carried out, including dynamic mechanical analysis, scanning electron microscopy, uniaxial tensile testing, and swelling study. These results show that increasing the BN content improves shape recovery efficiency significantly. Specifically, the 10 wt.% BN composites outperformed plain SMP in terms of shape recovery ratio when activated with FUS, and the highest shape recovery ratio can achieve 75%. However, higher BN content decreases crosslinking density and stiffness, as shown by a lower Young’s modulus and glass transition temperature. This study demonstrates the promise of BN-infused SMPCs for advanced applications in biomedical application, where noninvasive spatiotemporal actuation of SMPs is required. 

Abstract The main research goal of this study is to decipher the intercorrelation between process-induced thermal-structure-property relationships of Stainless Steel 316L fabricated by laser powder bed fusion. The objective therein is achieved by explaining and quantifying the effect of processing parameters and part-scale thermal history on microstructure evolution and mechanical properties of these parts. Multiple previous works have correlated the effect of process parameters on flaw formation, microstructural features evolved and functional properties; however, a lack of understanding remains in the underlying effect of the thermal history on part microstructure and mechanical properties. The thermal distribution, or thermal history, of the part as it is being built layer-by-layer is influenced by the processing parameters, material properties and shape of the part. The thermal history influences the microstructure by changing the grain structure evolution, which affects the part properties. Therefore, the novelty of this paper lies in illuminating the process-thermal history-microstructure-property relationship in laser powder bed fusion. Characterization of tensile specimens processed at a variety of conditions reveal a direct influence of the choice of process parameters on the dendritic structure and the grain orientations. A high energy density leads to <100> textured columnar dendritic grains and low energy density leads to randomly oriented equiaxed grains as a result of the shifting heat influx. The tensile properties are correlated with the inherent microstructure. Through future work involving fracture surface analysis, the texture, grain size and porosity is expected to influence the inherent fracture mechanism. This work demonstrates that an understanding of thermal distribution within a printed part can inform the choice of processing conditions to generate the final microstructure as per the specified functional requirements. Thus, this paper lays the foundation for future prediction and control of microstructure and functional properties in laser powder bed fusion by identifying the root fundamental thermal phenomena that influences the microstructure evolution and part properties. 

Abstract High-intensity focused ultrasound (HIFU) has been investigated as a remote and controlled activation method to noninvasively actuate shape memory polymers (SMPs), specifically in biomedical applications. However, the effects of aqueous environment on shape recoverability ofin vivoHIFU-actuated SMPs have yet to be explored. HIFU directs sound waves into a millimeter-sized tightly focused region. In this study, the response of hydrophilic and hydrophobic photopolymerized thermoset SMP networks under HIFU activation in an aqueous environment was investigated. Acrylate-based SMP networks were copolymerized in specific ratios to produce networks with independently adjusted glass transition temperatures ranging from 40 to 80 °C and two distinct water uptake behaviors. The results link the polymer swelling behavior to shape recoverability in various acoustic fields. The presence of absorbed water molecules enhances the performance of SMPs in terms of their shape memory capabilities when activated by HIFU. Overall, understanding the interplay between water uptake and HIFU-actuated shape recovery is essential for optimizing the performance of SMPs in aqueous environments and advancing their use in various medical applications. 

Fibrous shape memory polymers (SMPs) have received growing interest in various applications, especially in biomedical applications, which offer new structures at the microscopic level and the potential of enhanced shape deformation of SMPs. In this paper, we report on the development and investigation of the properties of acrylate-based shape memory polymer fibers, fabricated by electrospinning technology with the addition of polystyrene (PS). Fibers with different diameters are manufactured using four different PS solution concentrations (25, 30, 35, and 40 wt%) and three flow rates (1.0, 2.5, and 5.0 μL min −1 ) with a 25 kV applied voltage and 17 cm electrospinning distance. Scanning electron microscope (SEM) images reveal that the average fiber diameter varies with polymer concentration and flow rates, ranging from 0.655 ± 0.376 to 4.975 ± 1.634 μm. Dynamic mechanical analysis (DMA) and stress–strain testing present that the glass transition temperature and tensile values are affected by fiber diameter distribution. The cyclic bending test directly proves that the electrospun SMP fiber webs are able to fully recover; additionally, the recovery speed is also affected by fiber diameter. With the combination of the SMP material and electrospinning technology, this work paves the way in designing and optimizing future SMP fibers properties by adjusting the fiber diameter. 

Abstract Locomotion is a critically important topic for soft actuators and robotics, however, the locomotion applications based on two-way shape memory polymers (SMPs) have not been well explored so far. In this work, a crosslinked poly(ethylene-co-vinyl acetate) (cPEVA)-based two-way SMP is synthesized using dicumyl peroxide (DCP) as the crosslinker. The influence of the DCP concentration on the mechanical properties and the two-way shape memory properties is systematically studied. A Venus flytrap-inspired soft actuator is made by cPEVA, and it is shown that the actuator can efficiently perform gripping movements, indicating that the resultant cPEVA SMP is capable of producing large output force and recovering from large deformations. This polymer is also utilized to make a self-rolling pentagon-shaped device. It is shown that the structure will efficiently roll on a hot surface, proving the applicability of the material in making sophisticated actuators. With introducing an energy barrier, jumping can be accomplished when the stored energy is fast released. Finite element simulations are also conducted to further understand the underlying mechanisms in the complex behavior of actuators based on cPEVA SMP. This work provides critical insights in designing smart materials with external stimulus responsive programmable function for soft actuator applications.